Volume 1
- Lucy Leave (1966 Acetate) 2:55
- I'm A King Bee (1966 Acetate) 3:07
- Interstellar Overdrive (1966 Home Demo) 6:56
- Interstellar Overdrive (9-66 From ''san Francisco'' Soundtrack) 14:56
- Arnold Layne (2-67 Single) 2:56
- Candy And A Currant Bun (2-67 Single) 2:47
- Arnold Layne (2-67 Stereo Acetate) 2:38
- Candy And A Currant Bun (2-67 Stereo Acetate) 2:03
- Interstellar Overdrive (2-67 Stereo Acetate) 5:14
- Interstellar Overdrive (1967 ''tonite Let's All Make Love In London'') 16:50
- Nick's Boogie (1967 ''tonite Let's All Make Love In London'') 11:51
- See Emily Play (4-67 Acetate) 2:43
Volume 2
- See Emily Play (Single) 2:54
- Flaming (Us Single) 2:44
- Syd Barrett - Vegetable Man 2:32
- Scream Thy Last Scream 4:41
- Apples And Oranges (Single) 3:06
- Paintbox (Single) 3:48
- It Would Be So Nice (Single) 3:44
- Julia Dream (Single) 2:34
- Untitled Excerpt From ''the Committee'' 3:20
- Interstellar Overdrive (Live Rome 68-05-05) 6:44
- Careful With That Axe, Eugene (Stereo Single) 4:59
- Point Me At The Sky 3:41
- Embryo (From ''picnic'' Sampler) 4:41
- Biding My Time (From ''relics'') 5:18
- Main Theme From ''more'' 3:08
- Seabirds (From ''more'') 3:48
- Cymbaline (From ''more'') 5:19
- Heart Beat, Pig Meat (From ''zabriskie Point'') 2:57
- Come In Number 51, Your Time Is Up (From ''zabriskie Point'') 3:51
Volume 3
- Come In Number 51, Your Time Is Up (Stereo) 5:03
- Crumbling Land (Stereo) 4:13
- Heart Beat, Pig Meat (Stereo) 3:16
- Untitled (''zabriskie Point'' Outtake) 5:52
- Country Song (''zabriskie Point'' Outtake) 4:37
- Love Scene #1 (''zabriskie Point'' Outtake) 7:28
- Love Scene #2 (''zabriskie Point'' Outtake) 6:48
- Untitled (Aka Oenone) (''zabriskie Point'' Outtake) 6:21
- Untitled (Aka Fingal's Cave) (''zabriskie Point'' Outtake) 1:54
- Set The Controls For The Heart Of The Sun (Live Rotterdam 70-06-28) 3:06
- A Saucerful Of Secrets (Live Rotterdam 70-06-28) 6:38
- One Of These Days (Alternate Version #1) 4:39
- One Of These Days (Alternate Version #2) 6:34
Volume 4
- Echoes (Meddle Outtake) 21:09
- Opening Sequence From ''pompeii'' 3:37
- Mademoiselle Nobs (Aka Seamus) 1:54
- Brain Damage (''pompeii'' Soundtrack) 2:06
- Us And Them (''pompeii'' Soundtrack) 7:24
- On The Run (''pompeii'' Soundtrack) 3:29
- Money (Dsotm Outtake) 1:38
- Time (Dsotm Outtake) 6:13
- Brain Damage (Dsotm Outtake) 3:31
- Us And Them (Dsotm Outtake) 5:37
- Nick Mason - Here Comes Santa (1975 Demo) 2:14
- Shine On You Crazy Diamond (Wywh Outtake) 6:17
- Pigs On The Wing (Parts 1 & 2) (Animals Outtake) 3:21
- Comfortably Numb (The Wall Demo) 2:30