- Lucy Leave [1966 EMI acetate] 2:56
- King Bee [1966 EMI acetate] 3:05
- See Emily Play [alternate mix 1967 EMI acetate] 2:42
- Arnold Layne 2:54
- Candy And A Current Bun 2:42
- Flaming [alternate mix] 2:46
- Pow R Toc H / Astronomy Domine [4-May-67 BBC TV] 5:44
- Interstellar Overdrive [4-May-67 BBC TV] 5:03
- Reaction In G [July-1967 Radio Carlisle] 0:33
- Stoned Alone [live Denmark 13-Sept-1967] 5:18
- Vegetable Man 2:39
- Scream Thy Last Scream 4:37
- Apples And Oranges 3:01
- Baby Lemonade [Feb-1970 BBC] 2:20
- Dominoes [Feb-1970 BBC] 3:11
- Love Song [Feb-1970 BBC] 1:30
- Terrapin [live London 1-June-1970] 3:53
- Gigolo Aunt [live London 1-June-1970] 4:55
- Effervescent Elephant [live London 1-June-1970] 1:37
- Octopus [live London 1-June-1970] 4:53
- Octopus 3:44
- Jugband Blues [mono LP mix] 2:21
- Jugband Blues coda [mono LP mix] 0:37
- mystery track [non-Barrett] 0:19
Notes
Tracks 14-21: with David Gilmour (bass) and Jerry Shirley (drums)